It is suggested that the excellent sensing properties of Py-rGO-based sensors are governed by the intrinsic properties of rGO as well as adsorbed PPy molecules. On one hand, rGO sheets still have parts of oxygen-based moieties and structure defects after chemical reduction process, GSK2879552 solubility dmso which can Compound Library generally lead to the p-type semiconducting behavior of

the resultant rGO [29]. NH3, as a reducing agent, has a lone electron pair that can be easily donated to the p-type rGO sheets, leading to the increase of the resistance of the rGO devices. Since the rGO-based sensing devices studied in our work are fabricated by self-assembly technique, NH3 gas can interact with rGO sheets completely and result in excellent sensing performance of the devices during the testing process. On the other hand,

PPy molecules, as conducting polymers, can be generally considered as excellent NH3 gas sensing materials. Hence, the high throughput screening assay PPy molecules, which are attached on the surfaces of rGO sheets, play important roles in the enhancement of the sensing performance of the rGO devices and consequently show a better sensing performance than that of Hy-rGO devices. In addition, the repeatability of the Py-rGO sensing device has been studied as well. Figure  9 shows the relative resistance response of the assembled Py-rGO sensor as a function of time for detection of 10 ppm NH3 in four cycles, and the result suggests that the Py-rGO-based gas sensor exhibits a high reproducibility characteristic. Actually, the performance of the gas sensor based on Py-rGO is very stable for a long period time under normal

operating conditions. Even after several months, the sensing device still shows excellent sensing performance. Therefore, it is suggested that sensors based on self-assembled Py-rGO can be considered as excellent sensing devices and have great potential in the sensing areas. Figure 9 The repeatability properties of the assembled Py-rGO sensor exposed to 10 ppm NH 3 . Finally, the selectivity of the assembled Py-rGO-based gas sensor, as another key factor for the evaluation of sensing devices, has also been studied (Figure  10). The responses of the sensor based on assembled Py-rGO sheets to 1% of saturated concentration of different analytes, e.g., Oxalosuccinic acid DMMP, methanol, dichloromethane, hexane, chloroform, and xylene, have been studied and compared with the response of the device to 100 ppm NH3 gas. As shown in Figure  10, more than 2.3 times magnitude of response to 100 ppm NH3 gas for the Py-rGO sensor can be observed in comparison with other analytes. Since the concentration of NH3 gas is as low as 100 ppm while the concentrations of other analytes are much higher than that of NH3, it is suggested that the assembled Py-rGO-based sensor exhibits a high selectivity and can be considered as an excellent candidate for the detection of NH3 gas. Figure 10 Selectivity plot of the assembled Py-rGO sensing device.